Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Duplex stainless steelsthe duplex stainless steels were developed to exhibit comparable general corrosion resistance as 316ss, but with reduced susceptibility to chloride stress corrosion cracking. The influences of thermal treatment heat affected zone cases, composition, and microstructure on corrosion are given good coverage. Duplex stainless steel casting, 2205 duplex stainless. Grade 904l is nonmagnetic, and offers excellent formability, toughness and weldability. The corrosion resistance is a result of a very thin about 5 nanometers oxide layer on the steels surface. Stress corrosion cracking international institute of. Intergranular stress corrosion cracking behavior of.
Intergranular stress corrosion cracking of welded steel twi. Grade 904l contains high amounts of expensive ingredients, such as molybdenum and nickel. Molybdenum additions improve the stress corrosion cracking resistance of austenitic stainless steels significantly. Request pdf the effect of copper and molybdenum on pitting corrosion and stress corrosion cracking behavior of ultrapure ferritic stainless steels the work. Duplex 2304 is a 23% chromium, 4% nickel, molybdenum free duplex stainless steel whose structure is a balance of ferritic and austenitic. Effect of mo and cu on stress corrosion cracking of ferritic stainless. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. It finds applications due to both excellent corrosion resistance and high strength. High chromium and molybdenum concentrations provide this alloy with excellent corrosion resistance. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. The stress corrosion behaviour of molybdenum implanted. This gives it a high tensile strength which allows it to have better resistance to corrosion cracking and erosion, as well as having a high thermal conductivity and a low thermal expansion than conventional austenitic stainless steels. The microstructures consisted of second phases dispersed in a matrix of ferrite grains.
Molybdenum containing grades of stainless steels are generally more corrosion resistant than molybdenumfree grades. It has been found that scc resistance can be improved in some cases with the application of compressive stress to the material at risk. Highnickel alloys, such as alloy 600 or, better, commercially pure nickel uns n02201, are used for hot concentrated caustic. A complete guide to stainless steel metal casting resources. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Alloy ssc6mo superaustenitic stainless steel sandmeyer.
The addition of one or two percent molybdenum to ferritic stainless steels also significantly increases the corrosion resistance and the elevated temperature strength of these stainless steels. This mode of attack is termed stress corrosion cracking scc. Corrosion resistance of stainless steels molybdenum. Welded joints are one of the most complex objects from the standpoint of the general theory of corrosion fatigue of metals. Generally more resistant than 304 in range of atmospheric environments and many corrosive media due to the increased chromium and molybdenum content. The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. The combination of the high molybdenum and chromium content, along with the addition of tungsten, make alloy c276 nickel alloy plate highly resistant to chloride stress corrosion cracking, pitting, crevice corrosion and general corrosion. T1 effects of stress and temperature on stress corrosion cracking of austenitic stainless steels in concentrated magnesium chloride solutions.
Alloy c276 nickel alloy plate has excellent corrosion resistance in both oxidizing and reducing environments. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The effect of copper and molybdenum on pitting corrosion and. May 27, 2011 other forms of scc in stainless steels include caustic cracking and polythionic acid scc. Type 444 is dual stabilized with titanium and niobium. Chloride stress corrosion cracking in austenitic stainless. The article is about the material of stainless steel which is prodeminently used in food industries. Pdf stress corrosion cracking of stainless steel components in. Localized corrosion and stress corrosion cracking of stainless steels. The higher alloyed duplex stainless steel alloys, ones with significant molybdenum and nitrogen additions, can be superior to 316ss in certain. The effect of molybdenum mo content on the sulfide stress cracking ssc resistance of lowcarbon c, lowalloy steels in hydrogen sulfide h 2 ssaturated sodium chloride nacl solution was investigated by conducting a constantload test on four steels containing 0% to 0. Cracking of stainless steel nozzle sleeve metallurgical. High performance stainless steels nickel institute.
Chloride stress corrosion cracking ssina specialty steel. The result is a series of austenites, stronger than conventional 300 series stainless and with superior resistance to pitting, crevice corrosion, and stress corrosion cracking. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316. Chloride stress corrosion cracking in austenitic stainless steel.
Chloride stress corrosion cracks were also found at the corrosion sites. Experimental data from published literature on stress corrosion cracking scc of austenitic stainless steels ss as influenced by temperature and stress in concentrated chloride solutions were analyzed using the chemicalmechanical correlation model. The work addresses the influence of cu and mo additions on corrosion resistance of ferritic stainless steels in chloride media. Highly alloyed ironnickelchromium stainless steels containing. Although no stainless steel grade is totally immune. The alloy can be used as a corrosionresistant, high. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. The steel is also resistant to stress corrosion cracking and crevice corrosion. Highpurity hp type 304 ss was more susceptible to iascc than commercial purity cp type 304 ss in nwc at intermediate fluence.
Effects of stress and temperature on stress corrosion. Effect of molybdenum on sulfide stress cracking resistance. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The influence of molybdenum on stress corrosion in ultra. Stainless steels are more resistant to general corrosion compared with carbon steel. Corrosion assisted fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel summary.
Cu phases decreased the pitting corrosion resistance in chloride media. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Super duplex is a stainless steel mainly used in oil and gas applications. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. The composition of type 316 stainless steel includes slightly increased nickel content and the presence of 2%3% of molybdenum, which significantly increases the metals corrosion resistance. Penn stainless inventory now includes duplex 2507, which is a super duplex stainless steel with 25% chromium, 4% molybdenum, and 7% nickel. It has general corrosion resistance similar or better than alloys 304l and 316l but with yield strength nearly double that of austenitic stainless steels. Several chapters are spent on those special forms of corrosion that are investigated in the great detail in stainless steels, namely, pitting corrosion, crevice corrosion, and stress corrosion cracking. During their operation a number of problems arise related to the heterogeneity of the material properties, the. The effect of copper and molybdenum on pitting corrosion. Fractography analysis revealed significant changes in the cracking process both in the impact test and stress corrosion tests. Stress corrosion test the course of change in bend of the sample as a function of time was analyzed for all three heats and is shown in fig.
Test results indicate that alloy 22 is very resistant to chloride scc. The results of an investigation on the influence of molybdenum implantation on the electrochemical and stress corrosion cracking scc behaviour of aisi 304 l austenitic stainless steel are discussed. The influence of material factors on the intergranular stress corrosion cracking igscc susceptibility of austenitic stainless steels under hydrogenated hightemperature water were studied using the constant extension rate technique cert using specimens with a cold deformed hump. Stress corrosion cracking behavior of nickel base alloys. The influence of chromium on the atmospheric corrosion of low carbon steel ferrite is the basic crystal structure of iron or lowalloy steel at ambient temperatures.
Ak steel nitronic 19d stainless steel is a molybdenumfree, low nickel lean duplex stainless steel. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. The addition of both copper and molybdenum to 19% cr ferritic stainless steel causes stress corrosion cracking. The effect of molybdenum mo content on the sulfide stress cracking ssc resistance of lowcarbon c, lowalloy steels in hydrogen sulfide h 2ssaturated sodium chloride nacl solution was investigated by conducting a constantload test on four steels containing 0% to 0.
Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. After corrosion test the heat sign w1 with the lowest concentration of molybdenum cracking had ductility character both near the notch and in the central part of the sample, fig. Effect of molybdenum on sulfide stress cracking resistance of. Stainless steel is usually chosen because it is resistant against corrosionbut it is also chosen because it is steel. A cracked nozzle sleeve stub from a chemical processing vessel of the proprietary vaporizer system was analyzed to determine the cause of cracking. The influence of molybdenum on stress corrosion in ultra low. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. Type 316 uns s31600 stainless steel ss was much less susceptible to irradiationassisted stress corrosion cracking iascc than type 304 ss uns s30400 in nwc and hwc. Stress corrosion cracking in a brewery paul mueller company.
In the case of heats w1 and w2 the nature of stress corrosion processes is similar. Corrosion of unprotected carbon steel occurs even inside reinforced. Duplex stainless steel castings have lower nickel and molybdenum contents than their austenitic counterparts of similar corrosion resistance. Polythionic acid stresscorrosion cracking pascc is caused by sulfur. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. There is a steady growth in stress corrosion cracking, whereas in the case of w3 the process is different. These results are compared with a conventional molybdenum containing 316 l stainless steel and with the unimplanted aisi 304 l steel. Stainless steel, due to its superior corrosion resistance relative to most other metals, such as carbon steel and aluminum, becomes the cathode, accelerating the corrosion of the anodic metal. Stress corrosion cracking of stainless steels in nacl solutions. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stress corrosion cracking than the standard 300 series and standard duplex stainless steels. Stainless steel is known for its corrosion resistance in many environments in which carbon and low alloy tool steels would corrode. Adding 8% nickel to a ferritic chromium stainless steel makes an austenitic chromiumnickel stainless steel, for example type 304 stainless steel. The effect of molybdenum on sulfide stress corrosion cracking resistance has been studied for super martensitic stainless steels in sour environment at ph 3.
For example, molybdenum is considered to be detrimental in relation to. Super duplex alloys are characterised by a high chromium and molybdenum content. Jan 08, 2002 the duplex stainless steels, on the other hand, are more resistant to stress corrosion cracking scc than austenitic grades. Molybdenum primarily increases the corrosion resistance of stainless steels see grades and properties. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 122f 50c. The combination of strength, corrosion resistance, ease of forming and welding make ak steel nitronic 19d stainless steel a good choice in many applications. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Molybdenum effect on the sulfide stress corrosion of a. Failure analysis of corrosion on stainless steel fasteners. Corrosion of stainless steels stainless steels coursera. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The steel has excellent resistance to chloride stress. Stress corrosion cracking facts and how to reduce the risk.
Stress corrosion cracking occurs when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. The stress corrosion cracking scc susceptibilities of alloy 22 and type 316l stainless steel were evaluated in concentrated chloride solutions. Importance of molybdenum on irradiationassisted stress. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking scc is a common issue with many specialty alloys. That means molybdenum, nitrogen, and chromium are the most important alloying elements which can determine the pitting corrosion ability or resistance to pitting corrosion.
Three underlying factors must be present to cause scc. To understand it, envision a cube with an atom at each of the eight corners and in the geometric centre of the cube. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Caustic may crack carbon as well as stainless steel.
What differentiates 316 stainless steel from 304 stainless steel. Duplex 2304 is a 23% chromium, 4% nickel, molybdenumfree duplex stainless steel whose structure is a balance of ferritic and austenitic. In this chapter, the conditions for the occurrence of scc are first introduced. This alloy is designed for applications which require exceptional strength and corrosion resistance. Resistance to corrosion stainless steel tubing manufacturer. The use of 316l would be more resistant to crevice corrosion attack. The effect of copper and molybdenum on pitting corrosion and stress. There are reports on the stress corrosion cracking scc behavior of austenitic stainless steels in chloride and other corrosion solutions using various methods. Properties such as strength, yield, toughness, hardness, response to work hardening, weldability, and heattolerance make steel an incredibly useful metal in engineering, construction, and manufacturing, especially given its. An example is the corrosion of aluminum rivets fastening stainless steel sheets in contact with water. Stress corrosion cracking scc in stainless steels request pdf. Super austenitic stainless steels contain high levels of chromium and higher levels of nickel together with additions of molybdenum and nitrogen. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Stress corrosion cracking can be a problem under certain circumstances chlorides, humidity, elevated temperature for standard austenitic castings such as types 304 and 316 stainless steel castings.
Aisi 304 stainless steel around 8 %10% nickel content. Static proof rings test and dynamic slow strain rate traction measurements show that molybdenum appears to have a dual positive effect on stress corrosion resistance of super martensitic. The most susceptible austenitic grades have nickel contents in the. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. And the third form of corrosion of stainless steel is the stress corrosion cracking. Why are austenitic stainless steels more susceptible to. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. The chloride stresscorrosion cracking behavior of stainless steels.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This oxide layer is referred to as a passive layer since it renders the surface. Hence, the knowledge of its gradestypes, application, advantages and disadvantages of this important material is required for its safe and hygiene use today in the industrialized world to keep corrosion free surface. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stresscorrosion cracking than the standard 300 series and standard duplex stainless steels. The resistance of various commercial alloys to stress corrosion cracking scc in 50% naoh was evaluated at temperatures in the range 284 to 332 c.